Structure and Properties of Organic Molecules

Diethyl ether and butan-1-ol are isomers, and they have similar solubilities in water. Their boiling points are very different,however. Explain why these two compounds have similar solubility properties but dramatically different boiling points.

CH3CH2¬O¬CH2CH3 CH3CH2CH2CH2¬OH

diethyl ether, bp 35 °C butan-1-ol, bp 118 °C

8.4 mL dissolves in 100 mL 9.1 mL dissolves in 100 mL H2O

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